Catalytic allylic transfer reactions of functionalized aldehydes promoted by BINOL-Ti(IV) with synergistic reagent |
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| Authors: | Chan-Mo Yu Ji-Min KimMi-Sook Shin Daejin Cho |
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| Institution: | Department of Chemistry and BK-21 School of Molecular Science, Sungkyunkwan University, Suwon 440-746, Republic of Korea |
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| Abstract: | Practical and efficient catalytic asymmetric allylic transfer reactions of tin reagents promoted by BINOL-TiOCH(CF3)2]2 complex by the utilization of t-BuSBEt2 are successful with a variety of functionalized aldehydes containing ketone, aldehyde, ester, amide, or carbamoyl functionality and affords products in high levels of enantioselectivity. |
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