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Novel desilylation of alpha-dimethylsilyl esters by electrochemically generated superoxide ion |
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| Authors: | Christos KaimakliotisAlbert J Fry |
| Institution: | Chemistry Department, Wesleyan University, Middletown, CT 06459, USA |
| Abstract: | Electrochemical reduction of oxygen in the presence of an alpha-dimethylsilyl ester results in removal of the dimethylsilyl group. The reaction presumably proceeds by a mechanism involving electrochemically-generated superoxide ion. |
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