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Cross-metathesis of vinylsilanes carrying electron-withdrawing substituents with olefins in the presence of the second-generation Grubbs catalyst
Authors:Cezary Pietraszuk  Bogdan MarciniecHelmut Fischer
Affiliation:a Faculty of Chemistry, Adam Mickiewicz University, 60-780 Poznan, Poland
b Fachbereich Chemie, Universität Konstanz, Fach M 727, 78457 Konstanz, Germany
Abstract:The efficient cross-metathesis of vinylsilanes carrying electron-withdrawing substituents with various olefins is described. High yields and selectivities were obtained when styrene, 1-hexene, and selective functional allyl derivatives were used as the olefins.
Keywords:vinylsilanes   cross-metathesis   ruthenium   olefins
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