Synthesis and Crystal Structure of a Polymeric Cobalt(II) Complex with 1,2-bis(1,2,4-triazol-1-yl)ethane |
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| Authors: | Liang Shen Mengxian Luo |
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| Institution: | (1) College of Material Chemistry and Chemical Engineering, Hangzhou Normal University, Hangzhou, 310036, P.R. China |
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| Abstract: | Abstract The title complex Co2(bte)3(NCS)4(H2O)2]
n
(bte = 1,2-bis(triazol-1-yl)ethane) has been prepared. Single-crystal X-ray analysis reveals that the complex crystallizes
in space group P ī with a = 7.7962(2), b = 8.3407(4), c = 14.7735(5) ?, α = 86.835(2), β = 76.2031(9), γ = 80.583(3)°. The crystal consists of two discrete complexes, Co(bte)(NCS)2(H2O)2] and Co(bte)2(NCS)2]. The structure of Co(bte)(NCS)2(H2O)2] consists of neutral chain containing Co(II) bridged by bte molecules. The six-co-ordination of Co2+ is achieved by means of two trans NCS− ions and water molecules. The structure of Co(bte)2(NCS)2] demonstrates a one-dimensional neutral chain through bte-bridge, in which the Co(II) atom is in a distorted octahedral environment
formed by four nitrogen atoms of the triazoles and two nitrogen atoms from two trans thiocyanato liagnds.
Index abstract
Synthesis and Crystal Structure of a Polymeric Cobalt(II) Complex with 1,2-bis(1,2,4-triazol-1-yl)ethane
This paper reports the synthesis and crystal structure of complex Co2(bte)3(NCS)4(H2O)2]n (bte = 1,2-bis(triazol-1-yl)ethane), which consists two different neutral chains containing Co(II) bridged by bte molecules.
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| Keywords: | Cobalt(II) Bte-bridge Polymeric complex Crystal structure |
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