Polymer/clay nanocomposites through multiple hydrogen‐bonding interactions |
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| Authors: | Muhammed Aydin Tamer Uyar Mehmet Atilla Tasdelen Yusuf Yagci |
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| Institution: | 1. Department of Chemistry, Istanbul Technical University, Maslak, Istanbul, Turkey;2. UNAM‐Institute of Materials Science and Nanotechnology, Bilkent University, 06800 Ankara, Turkey;3. Department of Polymer Engineering, Faculty of Engineering, Yalova University, Turkey;4. Center of Excellence for Advanced Materials Research (CEAMR) and Department of Chemistry, Faculty of Science, King Abdulaziz University, Saudi Arabia |
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| Abstract: | An 2‐ureido‐41H]pyrimidinone (UPy) motif with self‐association capability (through quadruple hydrogen bonds) was successfully anchored onto montmorillonite clay layers. Polymer/clay nanocomposites were prepared by specific hydrogen bonding interactions between surface functionalized silica nanoclays and UPy‐bonded supramolecular poly(ethylene glycol) or poly(?‐caprolactone). The mixed morphologies including intercalated layers with a non‐uniform separation and exfoliated single layers isolated from any stack were determined by combined X‐ray diffraction and transmission electron microscopic measurements. Thermal analyses showed that all nanocomposites had higher decomposition temperatures and thermal stabilities compared with neat polymer. The differential scanning calorimetric data implied that the crystallinity of polymers did not show essential changes upon introduction of organomodified UPy clays. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015 , 53, 650–658 |
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| Keywords: | hydrogen bonding nanocomposites organoclay ring‐opening polymerization self‐assembly |
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