Dinitrogen activation, partial reduction, and formation of coordinated imide promoted by a chromium diiminepyridine complex |
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Authors: | Vidyaratne Indu Scott Jennifer Gambarotta Sandro Budzelaar Peter H M |
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Institution: | Department of Chemistry, University of Ottawa, Ottawa, Ontario, Canada. |
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Abstract: | Reduction of {2,6-2,6-(i-Pr)2PhN=C(CH3)]2(C5H3N)}CrCl (3) with NaH afforded the dinuclear dinitrogen complex {{2,6-2,6-(i-Pr)2PhN=C(CH3)]2(C5H3N)}Cr(THF)]2(mu-N2)}.THF (5). Reaction carried in exclusion of dinitrogen afforded instead deprotonation of the ligand with the formation of {2-2,6-(i-Pr)2PhN=C(CH3)]-6-2,6-(i-Pr)2PhNC=CH2](C5H3N)}Cr(THF) (4). Further reduction of 5 with NaH yielded a curious dinuclear compound formulated as {2,6-2,6-(i-Pr)2PhN=C(CH3)]2(C5H3N)}Cr(THF)]{2-2,6-(i-Pr)2PhN=C(CH3)]-6-2,6-(i-Pr)2PhNC=CH2](C5H3N)}Cr(THF)](mu-N2 H)(mu-Na)2 (6) containing two sodium atoms only bound to the dinitrogen unit and the pi systems of the two diiminepyridine ligands. Subsequent reduction with NaH triggered a complex series of events, leading to the formation of a species formulated as {2-2,6-(i-Pr)2PhN=C(CH3)]-6-2,6-(i-Pr)2PhNC=CH2](C5H3N)}Cr(mu-NH)]Na(THF)] (7) on the basis of crystallographic, spectroscopic, isotopic labeling, and chemical degradation experiments. |
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