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Spectroscopic characterization of Yb:Sc2O3 transparent ceramics
Authors:Lu Shen-Zhou  Yang Qiu-Hong
Affiliation:School of Materials Science and Engineering, Shanghai University, Shanghai 200072, China
Abstract:
Yb:Sc2O3 transparent ceramics are fabricated by a conventional ceramic process and sintering in H2 atmosphere. The room-temperature spectroscopic properties are investigated, and the Raman spectrum shows an obvious vibration characteristic band centred at 415 cm-1. There are three broad absorption bands around 891, 937, and 971 nm, respectively. The strongest emission peak is centred at 1.04 μm with a broad bandwidth (11 nm) and an emission cross-section of 1.8×10-20 cm2. The gain coefficient implies a possible laser ability in a range from 990 nm to 1425 nm. The energy-level structure shows that Yb:Sc2O3 ceramics have large Stark splitting at the ground state level due to their strong crystal field. All the results show that Yb:Sc2O3 transparent ceramics are a promising material for short pulse lasers.
Keywords:Yb:Sc2O3  transparent ceramics  spectroscopic properties
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