Synthesis and characterisation of some new cyanonitrosyl chromium(l) complexes with phenetidines and anisidines |
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| Authors: | Ram C Maurya Dinesh C Gupta Rajesh Shukla Raj K Shukla Nalmas Anandam Mannar R Maurya |
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| Institution: | (1) Department of Chemistry, Atarra P.G. College, 210201 Atarra, India;(2) Department of Chemistry, Regional Engineering College, Kurukshetra, 132119, India |
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| Abstract: | Summary A new series of cyano-substituted nitrosylchromium(I) complexes having octahedral stereochemistry around the metal ion, and of general formula, CrNO(CN)2(L)2(H2O)] (L =o-,m- andp-phenetidines oro-,m-, andp-anisidines) have been isolated in the solid state by interaction of potassium pentacy-anonitrosylchromate(I) monohydrate with the appropriately substituted aniline. The complexes, which have been characterised by elemental analysis, conductance, molecular weight determination, magnetic measurements, e.s.r. and i.r. spectral studies, contain chromium(I) in a low-spin d5-configuration. |
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