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Pretreatment processes for lignocellulosic biomass conversion to biofuels and bioproducts
Authors:Peter R Seidl  Adriana K Goulart
Institution:Escola de Química, Universidade Federal do Rio de Janeiro, Rio de Janeiro, RJ 21941-909, Brazil
Abstract:Lignocellulosic materials, such as forestry, agricultural and agroindustrial residues, are among the most important sources of biomass for the production of fuels, chemicals and materials. However there are physical and chemical barriers in the lignin–carbohydrate supramolecular structure that render most plant cell wall components almost completely unavailable for conversion into commercial products. Thus successful conversion strategies must lead to the disruption of this structure and result in partial or total separation of the lignocellulosic components, increasing the accessibility of cellulose, hemicelluloses and lignins. It must also minimize the formation of by-products. Each pretreatment technology has its own characteristics and is usually applied to a specific source of carbohydrates and lignins. A general overview of the most important pretreatment methods for the production of platform chemicals and fermentable sugars are given in this paper.
Keywords:Lignocellulosic pretreatment  Cellulose  Lignin  Sugar  Pulp  Bioproducts  AFEX"}  {"#name":"keyword"  "$":{"id":"kwrd0045"}  "$$":[{"#name":"text"  "_":"Ammonia fibre expansion  FDCA"}  {"#name":"keyword"  "$":{"id":"kwrd0055"}  "$$":[{"#name":"text"  "_":"2  5-furandicarboxylic acid  GVL"}  {"#name":"keyword"  "$":{"id":"kwrd0065"}  "$$":[{"#name":"text"  "_":"γ-valerolactone  HMF"}  {"#name":"keyword"  "$":{"id":"kwrd0075"}  "$$":[{"#name":"text"  "_":"5-hydroxymethyl  SPORL"}  {"#name":"keyword"  "$":{"id":"kwrd0085"}  "$$":[{"#name":"text"  "_":"sulfite pretreatment to overcome recalcitrance of lignocellulose  THF"}  {"#name":"keyword"  "$":{"id":"kwrd0095"}  "$$":[{"#name":"text"  "_":"tetrahydrofuran
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