Thermodynamic and structure studies of Gibbs films at soft interfaces |
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Authors: | Makoto Aratono Hiroki Matsubara Takanori Takiue |
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Institution: | (1) Department of Chemistry, Faculty of Science, Kyushu University, 6-10-1Hakozaki, Higashiku, Fukuoka 812-8581, Japan |
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Abstract: | The thermodynamic and X-ray reflectivity studies were applied to the adsorbed films of 1-eicosanol, partially hydrogenated
perfluorodecanol, and their mixtures at the hexane/water interface and clearly demonstrated the existence of domains. The
thermodynamic and FTIR studies on ethyleneglycol monododecyl ether system and the thermodynamic and total reflection XAFS
studies on dodecyltrimethylammonium bromide system at air/water interfaces confirmed that the inhomogeneous structure is rather
generally observed in the adsorbed films. The knowledge from the thermodynamic and structure studies has been combined and
further utilized in the mesoscopic thermodynamic formulation on the Gibbs films at soft interfaces. |
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Keywords: | |
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