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Development of a Novel Homogeneous and Heterogeneous Pd Catalytic System for Organic Transformations |
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| Authors: | Takahiro Nishimura and Sakae Uemura |
| Institution: | (1) Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Sakyo-ku, Kyoto, 606-8501, Japan;(2) Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Sakyo-ku, Kyoto, 606-8501, Japan |
| Abstract: | The results of our new finding on homogeneous and heterogeneous palladium catalytic system for oxidation of alcohols and alkenes using molecular oxygen are described together with several successful attempts to make the system recyclable from the viewpoint of environmental and economical concerns. In addition, some novel organic transformations of tert-cyclobutanols and cyclobutanone oximes are also presented where  -carbon elimination involving C–C bond fission is a key step. |
| Keywords: | palladium oxidation oxygen alcohol alkene cyclobutanol cyclobutanone oxime hydrotalcite fluorous biphase system |
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