The temperature dependence of the zero-field splitting of trimethylenemethane |
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| Authors: | Hiroshi Yoshida Ove Edlund |
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| Affiliation: | Faculty of Engineering, Hokkaido University, Kita-ku, Sapporo 060, Japan |
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| Abstract: | ![]()
Trimethylenemethane was generated by γ-irradiating polycrystalline methylenecyclopropane, and studied by EPR at various temperatures. The zero-field splitting constant, D, was observed to change from 0.0260 cm?1 at 4 K to 0.0212 cm?1 at 126 K, though the hyperfine coupling showed little temperature dependence. |
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