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Third virial coefficient and nonadditivity of the first-order repulsive interactions of rare-gas atoms
Authors:Andrzej Leś
Affiliation:Quantum Chemistry Laboratory, Institute of Basic Problems of Chemistry, University of Warsaw, 02-093 Warsaw, Poland
Abstract:
Corrections to the third virial coefficient derived from the first-order three-body exchange forces, ΔC1(T), in helium, neon and argon have been calculated. Inclusion of ΔC1 and the corrections due to the non-exchange three-body forces leads to a satisfactory agreement with experimental data.
Keywords:
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