Relationship between the longitudinal relaxation rates of water protons and of well defined paramagnetic centers at low temperature in hydrated vermiculite |
| |
| Authors: | D. Olivier P. Lauginie J.J. Fripiat |
| |
| Affiliation: | Laboratoire de Chimie des Solides, Université Pierre et Marie Curie, 75230 Paris Cedex, France;Centre de Recherche sur les Solides à Organisation Cristalline Imparfaite, C.N.R.S. 45045 Orléans Cedex, France |
| |
| Abstract: | A good agreement has been observed between the proton longitudinal relaxation rate in the two and one layer hydrate of the Na-Llano vermiculite, the location of the Fe3+ paramagnetic centers within the octahedral and tetrahedral layers of the lattice and the electronic longitudinal relaxation rate using the dipolar electronic—proton spin interaction. The water content influences noticeably the electronic longitudinal relaxation time. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
