Oxidizing supported reagents, I. Nature of the supported KMnO4 on solids |
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Authors: | M. S. Climent J. M. Marinas J. V. Sinisterra |
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Affiliation: | (1) Organic Chemistry Department, Faculty of Science, Cordoba, Spain;(2) Chemistry Department, EUITI, Cordoba, Spain |
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Abstract: | The nature of supported KMnO4 reagents on several solids (SiO2 AlPO4, BPO4 and sepiolite) is discussed. The oxidation of PhCHO to PhCO2H was the test reaction. The KMnO4 supported reagent is shown to be a mixture of physisorbed KMnO4 and Mn(IV). The influence of the nature of the solvent is discussed.
, (SiO2, AlPO4, BPO4 ). PhCHO PhCO2H. KMnO4 KMnO4 Mn(IV). . |
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