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Charging energy and stability of charged metallic particles
Affiliation:1. School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, GA, USA;2. Petit Institute of Bioengineering and Bioscience, Georgia Institute of Technology, Atlanta, GA, USA;1. Biosystems and Integrative Sciences Institute, Faculdade de Ciências, Universidade de Lisboa, 1749-016 Lisboa, Portugal;2. Departamento de Química e Bioquímica, Faculdade de Ciências, Universidade de Lisboa, 1749-016 Lisboa, Portugal;3. Research Unit for Molecular Medicine, Department of Clinical Medicine, Aarhus University and Aarhus University Hospital, 8200 Aarhus, Denmark;1. Department of Chemistry, University of Oxford, Chemistry Research Laboratory, Mansfield Road, Oxford OX1 3TA, UK
Abstract:
The stability of a charged metallic particle is investigated within the classical theory. The minimal number of atoms for which a charged spherical particle is stable against the spheroidal deformation, which relaxes the energy cost due to the Coulomb repulsion between extra charges, is derived. It is suggested that, for negatively charged particles, an extra electron virtually bound to particle is emitted before the fragmentation due to the Coulomb repulsion between extra charges will occur.
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