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Synthesis of a New Cyclophane Host and Crystal Structures of Its Compounds with Neutral Guests
Authors:N. Kent Dalley  Xiaolan Kou  Richard A. Bartsch  Bronislaw P. Czech  Piotr Kus
Affiliation:(1) Department of Chemistry and Biochemistry, Brigham Young University, Provo, Utah, 84602, U.S.A;(2) Department of Chemistry and Biochemistry, Texas Tech University, Lubbock, Texas, 79409, U.S.A
Abstract:
A new cyclophane host molecule 3 is prepared by connecting the oxygenatoms of twoagr,agrprime-di(4-hydroxyphenyl)-1,4-diisopropylbenzene units withtwo trimethylene spacers. Solid-state structures are determined forcompounds of 3 with dichloromethane and p-xylene guests. The crystals of thetwo host-guest compounds are isomorphous.
Keywords:Cyclophane  molecular receptor  inclusion compound  solid-state structure
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