Stereoconservative Negishi arylation and alkynylation as an efficient approach to enantiopure 2,2'-diarylated 1,1'-binaphthyls |
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| Authors: | Krascsenicsová Katarína Walla Peter Kasák Peter Uray Georg Kappe C Oliver Putala Martin |
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| Institution: | Department of Organic Chemistry, Faculty of Natural Sciences, Comenius University in Bratislava, Slovak Republic. |
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| Abstract: | Negishi arylation and alkynylation of easily synthesized chiral 2,2'-diodo-1,1'-binaphthyl rapidly proceeds in refluxing THF utilizing controlled microwave irradiation, affording enantiopure 2,2'-diarylated 1,1'-binaphthyls in good to excellent yields. |
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