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Applications of artificial intelligence for chemical inference—XXI: Chemical studies of marine invertebrates—XVII. The computer-assisted identification of [+]-palustrol in the marine organism Cespitularia sp., aff. subviridis
Authors:CJ Cheer  Dennis H Smith  Carl Djerassi  B Tursch  JC Braekman  D Daloze
Institution:Department of Chemistry, Stanford University, Stanford, CA 94305, U.S.A.;Collectif de Bio-écologie, Unité de Chimie Bio-organique, Université Libre de Bruxelles, Belgique
Abstract:In order to demonstrate the power utility of the interactive computer program CONGEN,5 an example describing its use in the identification of the tricyclic sesquiterpene alcohol, +]-palustrol, in extracts of a marine Xeniid (Cespitularia sp., aff subviridis) is provided. The rotation of +]-palustrol further supports the remarkable antipodal relationiship between sesquiterpenes from marine Coelenterates and their corresponding terrestrial forms.6
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