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1,2,4-triazines and condensed derivatives—XVI : 1-oxo-1,2-dihydro- and 1-oxo-1,2,6,7-tetrahydro[1,2,4]triazino[1,6-c]-quinazolin-5-ium salts. Synthesis and some reactions
Authors:G. Doleschall  K. Lempert
Affiliation:Research Group for Alkaloid Chemistry of the Hungarian Academy of Sciences, 1111 Budapest, Gellért tér 4. Hungary
Abstract:
Methylation of the type 1 and 2 triazinoquinazoliumolates yields the oxotriazinoquinazolinium salts of types 7 and 8, respectively. 4a similarly furnishes 9. Acid induced degradations and NaBH4 reductions of compounds 7–9, their conversions into the corresponding pseudobases (10, 11) as well as methods of synthesis of the novel oxotriazinoquinazoliniumolates (16) are described.
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