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Effect of structural phase transitions on the magnetic properties of sodium superoxide
Authors:S.D. Mahanti  A.U. Khan
Affiliation:Department of Physics, Michigan State University, East Lansing, MI 48824, U.S.A.;Departments of Chemistry and Biophysics, Michigan State University, East Lansing, MI 48824, U.S.A.
Abstract:
The dramatic temperature dependence of the magnetic susceptibility and Electron Spin Resonance in sodium superoxides between 77 and 300 K is attributed to various structural phase transitions. One of our important observations is a switchover from a weak ferromagnetically coupled 3-dimensional system to a strong antiferromagnetically coupled 1-dimensional system with decreasing temperature. There is no magnetic ordering.
Keywords:
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