Effect of structural phase transitions on the magnetic properties of sodium superoxide |
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Authors: | S.D. Mahanti A.U. Khan |
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Affiliation: | Department of Physics, Michigan State University, East Lansing, MI 48824, U.S.A.;Departments of Chemistry and Biophysics, Michigan State University, East Lansing, MI 48824, U.S.A. |
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Abstract: | ![]() The dramatic temperature dependence of the magnetic susceptibility and Electron Spin Resonance in sodium superoxides between 77 and 300 K is attributed to various structural phase transitions. One of our important observations is a switchover from a weak ferromagnetically coupled 3-dimensional system to a strong antiferromagnetically coupled 1-dimensional system with decreasing temperature. There is no magnetic ordering. |
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