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Distribution studies of metal ions on arsenophosphates of Sn(IV) and Cr(III) and on amine Sn(II) hexacyanoferrates (II) using radio tracers: Separation of Sr2+−Cs+, Hg2+−Ag+ and Hg2+−Zn2+
Authors:K G Varshney  S Naheed  A A Khan  S N Tandon  C B Gupta
Institution:(1) Chemistry Section, Z. H. College of Engineering and Technology, Aligarh Muslim University, 202001 Aligarh, India;(2) Chemistry Department, University of Roorkee, 247672 Roorkee, India
Abstract:Summary Distribution studies of some metal ions have been made on Sn(IV) and Cr(III) arsenophosphates and on some samples of Sn(II) amine hexacyanoferrates(II), using radiotracers. The Kd values of Cs+ and Rb+ have been followed at varying HNO3 concentrations also. As a result 3 useful binary separations have been achieved on Sn(IV) and Cr(III) arsenophosphates, such as Sr2+–Cs+, Hg2+–Ag+ and Hg2+–Zn2+.
Keywords:Distribution study  Radio tracer  Metal ions  Ion-exchange
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