Electrode kinetics of Eu3+/Eu2+ reaction by cyclic voltammetry |
| |
| Authors: | T P Radhakrishnan and A K Sundaram |
| |
| Institution: | (1) Analytical Chemistry Division, Bhabha Atomic Research Centre, 400085 Trombay, Bombay, India |
| |
| Abstract: | The cyclic voltammetric behaviour of Eu3+/Eu2+ couple at hanging mercury drop electrode (HMDE) has been studied in chloride, bromide, iodide, thiocyanate and EDTA supporting
electrolytes. The apparent rate constant and transfer coefficient for these systems have been calculated at various voltage
scan rates, without using the data for standard or formal potential. The values have been compared with those obtained by
earlier workers through other electrochemical methods. |
| |
| Keywords: | Cyclic voltammetry rate constant europium halides thiocyanate EDTA |
| 本文献已被 SpringerLink 等数据库收录！ |
|
