Synthesis of some novel sulfonyl ester derivatives derived from d-mannitol |
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| Authors: | Abdullah M Al Majid |
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| Institution: | Chemistry Department, College of Science, King Saud University, P.O. Box 2455, Riyadh 11451, Saudi Arabia |
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| Abstract: | The preparation of sulfonate-derivatives of d-mannitol i.e. 1,2:3,4-di-O-isopropylidene-3,4-di-O-p-toluenesulfonate-d-mannitol (3a), 1,2:3,4-di-O-isopropylidene-3,4-di-O-methanesulfonate-d-mannitol (3b), and 1, 2:3,4-di-O-isopropylidene-3,4-di-O-trifluoromethanesulfonate-d-mannitol (3c) is described. Full characterization and methodologies of these sulfonate-d-mannitol derivatives have been described as well. |
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| Keywords: | Sulfonyl ester Chiral compounds Bistosylate Chiral bidentate ligand Nucleophilic substitution |
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