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Synthesis,crystal structure and optical properties of quasi-one-dimensional lead (II) iodide: C14H18N2Pb2I6
Authors:K. Pradeesh  Monika Agarwal  K. Koteswara Rao  G. Vijaya Prakash
Affiliation:1. Nanophotonics lab, Department of Physics, Indian Institute of Technology Delhi, New Delhi-110016, India;2. Department of Chemistry, Indian Institute of Technology Delhi, New Delhi-110016, India;3. Department of Materials Science and Engineering, National Dong Hwa University, Hualien 974, Taiwan, ROC
Abstract:Quasi-one-dimensional lead (II) iodide compound, C14H18N2Pb2I6, with unique crystal structure was synthesized and solved for the crystal structure. These novel inorganic-organic hybrids have high thermal stability of upto 300 °C and show excitonic and charge-transfer features in their optical properties. An attempt has been made to understand the structural and optical mechanisms between inorganic one-dimensional polymeric PbI nano ribbons and the guest organic moiety for future applications in nanoscaled electronic devices.
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