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EPR and UV spectroscopic investigations of sucrose irradiated with heavy-ion particles
Authors:Yordanka Karakirova  Kouichi Nakagawa  Nicola D Yordanov
Institution:1. Laboratory EPR, Institute of Catalysis, Bulgarian Academy of Sciences, 1113 Sofia, Bulgaria;2. RI Research Center, Fukushima Medical University, 1 Hikarigaoka, Fukushima, 960-1295, Japan
Abstract:Crystalline sucrose irradiated with C and Si ions is investigated with EPR and UV spectroscopy. Samples are treated at different doses of radiation in the region 20–300 Gy and linear energy transfer (LET) values of 39.6, 49 and 58 keV μm?1 for C ions and 60 keV μm?1 for Si ions. All samples exhibit identical EPR spectra due to radiation-induced stable sucrose radicals. At given constant LET the EPR signal responses are linear to the absorbed doses of Si and C ions. Water solutions of irradiated sucrose exhibit UV absorption maximum at 267 nm due to the product of radical recombination. The intensity of this band is stronger at irradiation with Si than with C ions. UV absorption is more sensitive to heavy-ion species irradiation than the EPR signals.
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