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Chemistry of N‐Hydroxyguanidines: Photo‐Sensitized Oxygenation and Reaction with Nitric Oxide |
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| Authors: | Hiroyo Kabasawa Masako Ikeno Masahiro Suzukawa Keiro Higuchi Keiko Yanagisawa Hiroko Seki Tatsuhiro Tokunaga Tsutomu Ishikawa |
| Abstract: | The chemistry of N‐hydroxyguanidines, focusing on photo‐sensitized oxygenation and reaction with nitric oxide (NO), was examined. In the former reaction, a urea derivative was obtained as the main product together with the generation of NO. On the other hand, in the latter case, oxidative nitrosation occurred under aerobic conditions to give a nitrosourea derivative, which was also obtained from urea by the same treatment. |
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