锂原子光电离过程中的弛豫效应

利用基于多组态Dirac-Fock方法的程序包GRASP92和RATIP以及在此基础上最新发展的RERR06程序，计算了锂原子1s²nl(n=2,3; l=s, p) 的内壳层和外壳层的光电离截面. 计算中详细考虑了光电离过程中的弛豫效应. 结果表明：在锂原子内壳层电子的光电离过程中弛豫效应较强，而在外壳层电子的光电离过程中弛豫效应较弱. 另外，相应于不同态的内壳层光电离过程，其弛豫效应的影响也不同，对激发态的影响比对基态的影响大，对高激发态 关键词： 多组态Dirac-Fock方法 光电离截面 弛豫效应

Relaxation effect in photoionization processes of lithium

Using multi-configuration Dirac-Fock method and the corresponding packages GRASP92 and RATIP, as well as the newly developed RERR06, we calculated inner- and outer-shell photoionization cross sections of configurations 1s²nl(n=2,3; l=s, p) of atomic lithium. In the calculations, the relaxation effect caused by photoionization of electrons was included. It was found that the relaxation effect plays an important role in the inner-shell photoionizational processes, contrary to the outer-shell photoionizational processes. Further, the effects of relaxation on inner-shell photoionizational processes from different states are not the same. It is more prominent for the excited states than the ground state, and for the higher excited states than the lower excited states.