Nanoclusters based on pentagondodecahedra with shells in the form of <Emphasis Type="Italic">D</Emphasis>32, <Emphasis Type="Italic">D</Emphasis>42, and <Emphasis Type="Italic">D</Emphasis>50 deltahedra in crystal structures of intermetallic compounds |
| |
Authors: | A A Pankova G D Ilyushin V A Blatov |
| |
Institution: | 1.Samara State University,Samara,Russia;2.Shubnikov Institute of Crystallography,Russian Academy of Sciences,Moscow,Russia |
| |
Abstract: | The TOPOS software package has been used to form a database of intermetallic compounds containing pentagondodecahedral d clusters (528 crystal structures of intermetallic compounds, 111 topological types, and 47 space symmetry groups). On the
whole, 606 atomic d configurations have been selected which are described by 14 point symmetry groups. Examples of nanoclusters are presented
which are precursors of the crystal structures of intermetallic compounds with the outer shell in the form of deltahedra D, which are formed above dodecahedra. These nanoclusters are identified in the automatic mode of structural data processing:
D32 (K8In6Ge40, Cs30Na3Sn162), D
42 (Ru3Be17, Y3Cd18, Ca3(Cd17Al)), and D
50 (Yb3Zn18, Ce3(Au14Sn3), Pr3Cd18, Eu4Cd25), where 32, 42, and 50 are the numbers of atoms in the shell. Similar deltahedra were found previously in icosahedral nanoclusters
(precursors of intermetallic compounds). Structures with the dodecahedral nanocluster precursors containing D42 and D50 deltahedra are approximants of MCd5.7 (M = Yb or Ca) quasicrystals and belong to the family of MCd6 (M = Ce, Pr, Nd, Sm, Eu, Gd, Dy, Yb, Y, or Ca). |
| |
Keywords: | |
本文献已被 SpringerLink 等数据库收录! |
|