| 新型多氢键双功能手性酰胺类化合物的高效合成 |
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| 引用本文： | 裴学海,黄克俊,尹晓刚,陈治明.新型多氢键双功能手性酰胺类化合物的高效合成[J].合成化学,2017,25(8):648-652. |
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| 作者姓名： | 裴学海 黄克俊 尹晓刚 陈治明 |
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| 作者单位： | 贵州师范大学 化学与材料科学学院 贵州省功能材料化学重点实验室，贵州 贵阳 550001 |
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| 基金项目： | 国家自然科学基金资助项目，贵州省自然科学基金资助项目 |
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| 摘 要： | 以BINOL-3,3′-二羧酸为原料，经外消旋化合物的拆分和缩合反应，合成了7个新型的联二萘骨架手性酰胺类化合物，收率51%~70%，其结构经1H NMR, 13C NMR, FT-IR, HR-MS（ESI）和元素分析表征。
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| 关 键 词： | BINOL-3 3&prime -二羧酸 手性酰胺 手性配体 联二萘 合成 |
| 收稿时间： | 2017-02-02 |
Highly Efficient Synthesis of Novel Multiple Hydrogen-bonding and Bifunctional Chiral Amides Compounds |
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| PEI Xue-hai,HUANG Ke-jun,YIN Xiao-gang,CHEN Zhi-ming.Highly Efficient Synthesis of Novel Multiple Hydrogen-bonding and Bifunctional Chiral Amides Compounds[J].Chinese Journal of Synthetic Chemistry,2017,25(8):648-652. |
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| Authors: | PEI Xue-hai HUANG Ke-jun YIN Xiao-gang CHEN Zhi-ming |
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| Institution: | Key Laboratory of Functional Materials Chemistry of Guizhou Province, School of Chemistry and Materials Science, Guizhou Normal University, Guiyang 550001, China |
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| Abstract: | Seven novel binaphthyl backbone chiral amides compounds were synthesized by resolution of the coupled racemic and condensation, using BINOL-3,3′-dicarboxylic acid as starting material.The yields were 51%~70%.The structures were characterized by 1H NMR, 13C NMR, FT-IR, HR-MS(ESI) and elemental analysis. |
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| Keywords: | BINOL-3 3′-dicarboxylic acid chiral amide chiral ligand binaphthyl synthesis |
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