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| 配合物[Cu(PTA)(phen)2]·(PTA)·(H2O)4的合成、晶体结构及电化学性质 | |
| 引用本文： | 李薇,李昶红,杨颖群,邝代治,陈志敏,徐伟箭,陈满生. 配合物[Cu(PTA)(phen)2]·(PTA)·(H2O)4的合成、晶体结构及电化学性质[J]. 无机化学学报, 2006, 22(1): 101-105 |
| 作者姓名： | 李薇 李昶红 杨颖群 邝代治 陈志敏 徐伟箭 陈满生 |
| 作者单位： | 1. 衡阳师范学院化学与材料科学系,衡阳,21008;湖南大学化学化工学院,长沙,410082 2. 湖南工学院化工系,衡阳,421008 3. 衡阳师范学院化学与材料科学系,衡阳,21008 4. 湖南大学化学化工学院,长沙,410082 |
| 基金项目： | 湖南省基础性研究项目;湖南省教育厅科研项目;衡阳师范学院校科研和教改项目 |
| 摘 要： | The title complex has been synthesized by using terephthalic acid (PTA), 1,10-phenanthroline (phen) and copper monohydrate. It crystallizes in monoclinic space group C2/c with a=2.959 0(2) nm, b=1.466 4(10) nm, c=1.764 3(12) nm, β=105.593(11)°, V=7.372(9) nm3, Dc=1.489 g·cm-3, Z=8, F(000)=3 416, R1=0.043 6, wR2= 0.151 9. The crystal structure shows that the copper atom is coordinated with four nitrogen atoms from two phens and one oxygen atom from one terephthalic acid, forming a distorted square-pyramid coordination geometry. The cyclic voltametric behavior of the complex is also reported. CCDC: 277047. |
| 关 键 词： | 铜(II)配合物； 晶体结构； 电化学性质 |
| 文章编号： | 1001-4861(2006)01-0101-05 |
| 收稿时间： | 2005-04-25 |
| 修稿时间： | 2005-09-22 |
Synthesis, Crystal Structure and Electrochemical Properties of Copper(Ⅱ) Complex [Cu(PTA)(phen)2]·(PTA)(H2O)4 |
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| LI Wei,LI Chang-Hong,YANG Ying-Qun,KUANG Dai-Zhi,CHEN Zhi-Ming,XU Wei-Jian and CHEN Man-Sheng. Synthesis, Crystal Structure and Electrochemical Properties of Copper(Ⅱ) Complex [Cu(PTA)(phen)2]·(PTA)(H2O)4[J]. Chinese Journal of Inorganic Chemistry, 2006, 22(1): 101-105 | |
| Authors: | LI Wei LI Chang-Hong YANG Ying-Qun KUANG Dai-Zhi CHEN Zhi-Ming XU Wei-Jian CHEN Man-Sheng |
| Affiliation: | Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang, Hunan 421008;College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082,Department of Chemical Engineering, Hunan Institute of Technology, Hengyang, Hunan 421008,Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang, Hunan 421008;College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082,Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang, Hunan 421008,Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang, Hunan 421008,College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082 and Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang, Hunan 421008 |
| Abstract: | |
| Keywords: | copper(II) complex crystal structure electrochemical property |
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