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Un-catalyzed oxidation of cyclic ketones by alkaline hexacyanoferrate(III) - Kinetic evidence for the formation of hydrates
Authors:Praveen K. Tandon   Santosh Kumar   Alok K. Singh  Nidhi Srivastava
Affiliation:(1) Department of Chemistry, University of Allahabad, Allahabad, 211002, India
Abstract:Hydrate formation by cyclic ketones confirmed by kinetic and spectral studies shows reduction of hexacyanoferrate(III) after the slow step. Orders and rate constants were confirmed by various methods.
Keywords:Cyclic ketones  oxidation  hydrates  hexacyanoferrate
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