Paradoxes and paradigms: influence of the power of z on the estimation of entropies of formation of aqueous anions using simple parameters |
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Authors: | Maja Ponikvar-Svet Joel F Liebman |
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Institution: | (1) Department of Inorganic Chemistry and Technology, Jožef Stefan Institute, Jamova 39, 1000 Ljubljana, Slovenia;(2) Department of Chemistry and Biochemistry, University of Maryland, Baltimore County, Baltimore, MD 21250, USA |
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Abstract: | We continue our use of “simple” energetic patterns, where simple means the use of parameters derived only from the stoichiometry
of these species in our studies of the entropy of formation (TΔf
S
o) of aqueous anions. Relationships between the entropy of formation and different parameters such as the number of oxygen
atoms, the natural logarithm of the molecular weight and the total number of atoms are explored. The charge of the species,
z− continues to be explicitly considered where we now explore various choices of p and use of z
p as a parameter. |
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Keywords: | Anions Aqueous Entropy Ionic charge Patterns Powers of z Statistics |
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