Protonation and bromination of an osmabenzyne: reactions leading to the formation of new metallabenzynes |
| |
| Authors: | Wen Ting Bin Ng Sze Ming Hung Wai Yiu Zhou Zhong Yuan Lo Man Fung Shek Lai-Yung Williams Ian D Lin Zhenyang Jia Guochen |
| |
| Affiliation: | Department of Chemistry, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong. |
| |
| Abstract: | ![]()
The reactivities of benzynes and metal-carbyne complexes are normally associated with the triple bond units. However, we have now found that electrophiles do not attack the formal osmium-carbon triple bond of osmabenzyne complex 1. Instead, 1 undergoes electrophilic substitution reactions-the typical reactions of aromatic systems. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
