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Substituent Effect on Absorption and Fluorescence Properties of Thieno[3, 2-<Emphasis Type="Italic">c</Emphasis>]Pyridine Derivatives
Authors:Sunil N Chavan  Raghunath B Toche  Satish M Chavan
Institution:1.Department of Chemistry,KRT Arts BH Commerce & AM Science College,Nashik,India;2.Department of Chemistry,RNC Arts, JDB Commerce & NSC Science College,Nashik,India;3.Savitribai Phule Pune University (Formerly University of Pune),Pune,India
Abstract:New substituted thieno3,2-c]pyridine derivatives 5 were synthesized by the reaction of 3-bromo-4-chlorothieno3,2-c]pyridine 1 with cyclic amine 2, which further on Suzuki reaction with boronic acids 4 converted to corresponding 3-arylthieno3,2-c]pyridine 5. Substituent R3 has predominant effect on fluorescence properties of thienopyridines. However, the electron donor amine at C4 has no effect on fluorescence properties of thienopyridines.
Graphical Abstract New thieno3,2-c]pyridine derivatives were synthesized from 3-bromo-4-chlorothieno3,2-c]pyridine and cyclic amines, which by on Suzuki reaction with boronic acids converted to corresponding 3-arylthieno3,2-c]pyridine. Substituent R3 has predominant effect on fluorescence properties of thienopyridines. However, the electron donor amine at C4 has no effect on fluorescence properties of thienopyridines
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