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Polymeric Three-Dimensional Crystal Structure of a Tributyltin(IV) Derivative with Acetylene Dicarboxylic Acid |
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| Authors: | Shabbir Hussain Saqib Ali Saira Shahzadi Corrado Rizzoli |
| Institution: | 1. Department of Chemistry , GC University , Faisalabad , Pakistan;2. Department of Chemistry , Quaid-i-Azam University , Islamabad , Pakistan;3. Dipartimento di Chimica Generale ed Inorganica , Chimica Analitica, Chimica Fisica, Parco Area delle Scienze 17/A , Parma , Italy |
| Abstract: | Abstract A novel polymeric complex has been synthesized by refluxing disodium acetylene dicarboxylate with tributyltin chloride in dry methanol. The solid-state structure of the complex has been determined by single-crystal X-ray analysis. The tin(IV) metal exhibits distorted trigonal bipyramidal geometry. Each carboxylate group of the ligand acts in a bidentate fashion, linking adjacent metal atoms to produce polymeric chains, which are cross-linked into a three-dimensional network. |
| Keywords: | Acetylene dicarboxylic acid tributyltin(IV) derivative polymeric three-dimensional crystal structure |