Resolution of 5- and 6-Membered P-Heterocycles: Racemic and Optically Active Platinum(II)-3-Phospholene Complexes |
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| Authors: | Péter Bagi Tamara Kovács Andrea Laki András Fekete Elemér Fogassy György Keglevich |
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| Affiliation: | Department of Organic Chemistry and Technology , Budapest University of Technology and Economics , Budapest , Hungary |
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| Abstract: | ![]()
Abstract Methods were developed for the resolution of several five- and six-membered phosphorus heterocycles (1c-e, 2, 4). It was investigated if the optical activity is preserved during the 1a→2→3→4 reaction sequence. Racemic and optically active 1b-e 3-phospholene 1-oxides were converted to the corresponding platinum-complexes (10b-e), which are potential catalysts. |
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| Keywords: | 3-Phospholene oxide 3-phosphabicyclo[3.1.0]hexane oxide 1,2-dihydrophosphinine oxide 1,2,3,6-tetrahydrophosphinine 1-oxide a resolution platinum complex |
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