Studies on Poly(Dialkoxyphosphazenes) for the Medical Applications |
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| Authors: | Wiesław Sulkowski Anna Sułkowska Viatsheslav Kireev |
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| Affiliation: | 1. Institute of Environmental Engineering, Technical University , Czehowa, Poland;2. Biophysical Chemistry Department , Medical University School , Sosnowiec, Poland;3. Macromolecular Chemistry Department , Moscow D.I. Mendeleev University of Chemical Technology , Moscow, Russia |
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| Abstract: | Abstract The presence of trace of chlorine in poly(diorganophosphazenes) [-N=P(OR)2-]., where R = C2H5, CH2CF3, C2F5, C4H5, C6H13, C8H17, C12H25, CH2C6H5 in many cases leads to the substantial changes of their physicochemical properties and limits application possibilities of this class of polymers especial for the medical materials. Despite the optimization of reaction conditions for each nucleophilic alkoxy substituent, the obtained poly(dia1koxyphosphaenes) exhibited some physicochemical anomalies. |
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| Keywords: | poly(dichlorophosphazene) poly(dialkoxyphosphazenes) substitution physicochemical properties medical application NMR studies dielectric properties |
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