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Metal-Rich Phosphanediyl-and Arsanediyl-Clusters |
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| Authors: | Klaus Merz Stefan Martin Vassili Pintchouk Hans Pritzkow Matthias Driess |
| Affiliation: | Chair of Inorganic Chemistry I , University Bochum , D-44801 , Bochum , Germany |
| Abstract: | Abstract The reactions of primary silylphosphanes and -arsanes 1 with BuLi yield the three-dimensional M2ER-aggregates 2 (E = P, As). We observed that the double lithiation of 1 in the presence of Li2O results in the formation of the aggregates 3 and 4. |
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