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Facile and Convenient Synthesis of 5-Arylalkylidenerhodanines by Electrocatalytic Crossed Aldol Condensation
Authors:Hojat Veisi  Zahra Vafajoo  Behrooz Maleki  Malek Taher Maghsoodlou
Institution:1. Department of Chemistry , Payame Noor University , Tehran , Iran;2. Department of Chemistry , The University of Sistan and Baluchestan , Zahedan , Iran;3. Department of Chemistry , Hakim Sabzevari University , Sabzevar , Iran
Abstract:Abstract

An electrochemically induced catalytic crossed Aldol condensation of one equivalent of rhodanine with various aromatic aldehydes and ketones in ethanol in an undivided cell in the presence of sodium bromide as an electrolyte results in the formation of the corresponding 5-arylalkylidenerhodanines in 80–96% yield with reactions in 40 min.

Supplemental materials are available for this article. Go to the publisher's online edition of Phosphorus, Sulfur, and Silicon and the Related Elements to view the free supplemental file.
Keywords:Electrocatalysis  aldol condensation  rhodanine  aldehydes  ketones
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