C-Phosphorylation of Electron-Rich Heterocycles |
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Authors: | Andrew A Tolmachev Sergei P Ivonin Alexandra A Chaikovskaya Tamara N Kudrya Tat'jana E Terekovskaya |
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Institution: | Institute of Organic Chemistry of the Ukrainian National Academy of Sciences , Murmanskaya Str., 5, KIEV-94, 253660, UKRAINE |
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Abstract: | Abstract C-phosphorylation of pyrrole, furan, thiophene derivatives and their benzanalogs by phosphorus tribromide has been studied. Perspective methods for involving trivalent phosphorus residues at a different position of the rings have been developed. Unknown early the heterocycle's derivatives with tri- and tetracoordinated phosphorus substituents (1–5) and novel types of phosphoruscontaining heterocycles (6,7) have been obtained. |
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