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STUDIES ON ORGANOPHOSPHORUS COMPOUNDS XLIV. STRUCTURAL EFFECT OF ELECTROPHILES ON THE REGIOSELECTIVITY OF CARBANION DERIVED FROM DIALKYL ALLYLPHOSPHONATES
Authors:Chengye Yuan Jiachang Yao  Shusen Li
Affiliation:Shanghai Institute of Organic Chemistry, Academia Sinica , 345 Linglin Lu, Shanghai, 200032, China
Abstract:
Abstract

For the evaluation of the structural effect of electrophiles on the regioselectivity of ambident anions, the reaction of phosphoryl allylic carbanion with p-substituted benzaldehydes was investigated.
Keywords:Allylphosphonate carbanion  regioselectivity  structural effect of electrophiles
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