Synthesis,Crystal Structure,and Characterization of A New Hydrogen Phosphate Templated By 3-Aminophenyl Sulfone

Abstract

The synthesis and crystal structure of a new noncentosymmetric compound with the general formula: [C₄₈H₅₁N₈O₈S₄](HPO₄)H₂PO₄ are reported. The structure, determined by single-crystal X-ray diffraction at 150 K can be described as organic layers [C₄₈H₅₁N₈O₈S₄]³⁺ parallel to the (a and c) plane between which the inorganic groups consisting of H₂PO₄ ^? and HPO₄ ^2? entities are inserted as inorganic layers. In this atomic arrangement, H-bonds and Vander-Waals interactions between the different species play an important role in the tridimensional network cohesion. Solid-state ¹³C and ³¹P MAS NMR spectroscopies are in agreement with the X-ray structure.

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