Structural,Vibrational, Thermal,and Electrochemical Studies of a Cyclohexaphosphate Complex, (C5H14N2)2Cd2CL2P6O18.4H2O |
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| Authors: | I. Ameur S. Abid S. Besbes-Hentati S. S. Al-Deyab M. Rzaigui |
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| Affiliation: | 1. Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, 7021 Zarzouna , Bizerte , Tunisia;2. Petrochemical Research Chair, College of Science, King Saud University , Riyadh , Saudi Arabia |
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| Abstract: | Abstract A novel cadmium cyclohexaphosphate (C5H14N2)2Cd2Cl2P6O18.4H2O has been prepared and characterized by single-crystal X-ray diffraction, infrared and Raman spectroscopies, thermogravimetric analysis, and cyclic voltammetry. The structure consists of vertex linked of CdO5Cl octahedral and P6O18 rings assembled into a two-dimensional macroanionic layers. Organic double-protonated homopiperazine cations are located between these layers and interact with the framework both electrostatically and via hydrogen bonds of N–H···O(Cl). [Supplemental materials are available for this article. Go to the publisher's online edition of Phosphorus, Sulfur, and Silicon and the Related Elements to view the following free supplemental files: Additional figures] |
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| Keywords: | Crystal structure cyclohexaphosphate IR spectroscopy thermal analysis X-ray diffraction cyclic voltammetry |
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