31P NMR Spectral Evidence for the Hexacoordinated Phosphorus Intermediates in the Reaction of Oxyphosphorochloridate With Amino Acids |
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| Authors: | Zhaolong Li Hua Fu Hegui Gong Yufen Zhao |
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| Affiliation: | Bioorganic Phosphorus Laboratory, Department of Chemistry , Tsinghua University , Beijing , 100084 , P.R. China |
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| Abstract: | Abstract The nucleophilic groups on the side chain of amino acid can attack phosphoryl to form high-coordinated phosphorus intermediate. which was similar to the active sits of the CAMP-enzyme system [1, 2] |
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