Polarity and Conformations of Phosphazacompounds in Solution |
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| Authors: | Zhanneta R Gulyaeva Igor I Patsanovsky Eleonora A Ishmaeva Lech Stefaniak Wojciech Domalewski |
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| Institution: | 1. Kazan State University , Kazan, 420008, Russia;2. Institute of Organic Chemistry PAS , Warshawa, Poland |
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| Abstract: | Abstract A series of iminophosphoranes o-X-C6H4-N=PPh3, where X=H(I),Me (II),Et (III),OMe(IV),OEt(V) were investigated by means of dipole moments method. Because of an orientation of aromatic fragment determines intramolecular interactions in the system (benzene ring - double N=P bond), the problem of internal rotation of N-Car bond is important. DM (exp.) of molecules (I-V), determined in dioxane are 4.30(I), 4.34(II), 4.53(III), 4.75(IV), 4.79 D(V), respectively. |
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