| 含NS和NNSS供电子原子的钌(Ⅱ)羰基配合物 |
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| 作者姓名： | DanielThangadurai.T Son-KiIhm |
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| 作者单位： | Department of Chemical and Biomolecular Engineering, Korea Advanced Institute of Science and Technology, 373-1 Guseong-dong, Yuseong-gu, Daejeon 305-701, Republic of Korea,Department of Chemical and Biomolecular Engineering, Korea Advanced Institute of Science and Technology, 373-1 Guseong-dong, Yuseong-gu, Daejeon 305-701, Republic of Korea |
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| 基金项目： | We gratefully acknowledge the financial support from the Brain Korea 21 Project and National Research Laboratory for Environmental Catalysis. |
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| 摘 要： | 通过RuHCl(CO)(PPh3)2(B)] (B=PPh3, 吡啶 (py), 哌啶 (pip), 吗啉 (morph))与适当的席夫碱按1∶1的物质的量的比反应，合成了二齿和四齿席夫碱钌(Ⅱ)配合物。所用席夫碱配体通过S-苄基二硫代肼基甲酸酯与2,3-丁二酮(物质的量的比分别为1∶1和1∶2)的缩合反应制得。通过元素分析和多种物理化学方法对钌(Ⅱ)配合物和其席夫碱配体进行了表征。钌(Ⅱ)配合物为六配位的反磁性物质。用三种细菌对席夫碱配体及其钌(Ⅱ)配合物的抗微生物活性进行了筛选试验。
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| 关 键 词： | 钌(Ⅱ) 羰基配合物 席夫碱 供电子体 |
| 文章编号： | 1001-4861（2006）06-1055-07 |
| 收稿时间： | 2006-02-02 |
| 修稿时间： | 2006-04-27 |
Ruthenium(Ⅱ) Carbonyl Complexes Containing NS and NNSS Donor Atoms |
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| DanielThangadurai.T,Son-KiIhm.Ruthenium(Ⅱ) Carbonyl Complexes Containing NS and NNSS Donor Atoms[J].Chinese Journal of Inorganic Chemistry,2006,22(6):1055-1061. |
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| Authors: | Daniel Thangadurai T and Son-Ki Ihm |
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| Institution: | 1. Center for Superfunctional Materials, Department of Chemistry, Pohang University of Science and Technology San 31,Hyojo-gu, Pohang 790-784, Republic of Korea
2. Department of Chemical and Biomolecular Engineering, Korea Advanced Institute of Science and Technology, 373-1 Guseong-dong, Yuseong-gu, Daejeon 305-701, Republic of Korea |
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| Abstract: | Bidentate and tetradentate Schiff base ruthenium(Ⅱ) complexes has been synthesized by the reaction of RuHCl(CO)(PPh3)2(B)] (B=PPh3 or pyridine (py) or piperidine (pip) or morpholine (morph)) with appropriate Schiff bases in 1:1 molar ratio. The Schiff base ligands were prepared by condensing S-benzyldithiocarbazate (NH2NHCSSCH2C6H5) with 2,3-butanedione (1:1 and 1:2 molar ratio). Ruthenium(Ⅱ) complexes and the ligands were studied and characterized by elemental analyses and various physico-chemical methods. The ruthenium complexes were diamagnetic with six-coordinate structures. The ligands and the complexes were screened for antimicrobial activity against three organisms. |
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| Keywords: | carbonyl complexes Schiff base donor atom |
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