Reaction of succinonitrile with aliphatic amines |
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Authors: | V A Keppen V N Andronov M A Andreeva V M Karysheva D S Zhuk |
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Institution: | (1) A. V. Topchiev Institute of Petrochemical Synthesis, Academy of Sciences of the USSR, USSR |
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Abstract: | Conclusions The reaction of primary amines with succinonitrile leads to the formation of N,N,N,N-tetrasubstituted amidines and the liberation of 2 M of NH3. The reaction of secondary amines with succinonitrile proceeds as an intramolecular condensation with the liberation of 1 M of NH3 per mole of the dinitrile and the formation of the 2,5–, -dialkylaminopyrrolene.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2722–2725, December, 1973. |
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