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Synthesis of an asymmetric fullerene dimer via sequential cycloadditions |
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| Authors: | Timothy J Hingston Nicholas H Rees G Andrew D Briggs |
| Institution: | a Department of Materials, University of Oxford, Parks Road, Oxford, OX1 3PH, UK b Chemistry Research Laboratory, Department of Chemistry, University of Oxford, South Parks Road, Oxford, OX1 3TA, UK |
| Abstract: | A single isomer of a monofunctionalised C70 fullerene is isolated and characterised using variable temperature NMR spectroscopy. Pendant methylene bromide groups allow for further cycloaddition reactions and a C60-C70 asymmetric fullerene dimer is thus prepared. |
| Keywords: | Fullerenes Dimers Cycloadditions |
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