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Asparinins, asparosides, curillins, curillosides and shavatarins: structural clarification with the isolation of shatavarin V, a new steroidal saponin from the root of Asparagus racemosus
Authors:Patricia Y Hayes  Reg Lehmann  William Kitching
Institution:a Chemistry, SMMS, The University of Queensland, Chemistry Department, Brisbane, Qld 4072, Australia
b MediHerb Research Laboratories, Brisbane Technology Park, Qld 4113, Australia
Abstract:A new steroidal saponin, shatavarin V, (3-O-{α-l-rhamnopyranosyl(1→2)]β-d-glucopyranosyl(1→4)]-β-d-glucopyranosyl}-(25S)-5β-spirostan-3β-ol), was isolated from the roots of Asparagus racemosus by RP-HPLC, and its structure determined by 1D and 2D NMR studies. This data permits clarification of the structures reported for several known saponins: asparinins A and B; asparosides A and B; curillin H; curillosides G and H and shavatarins I and IV.
Keywords:Asparagus racemosus  Shatavarin V  Shatavarins I and IV  Asparinins A and B  Asparosides A and B  Curillin H  Curillosides G and H  NMR
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